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From 2004 to 2005, the group produced a double album, Mezmerize/Hypnotize with the two parts released six months apart. The first album, Mezmerize, was released on May 17 2005, to favorable reviews by critics. It debuted at #1 in the United States, Canada, Australia and all around the world, making it System of a Down's second #1 album. First week sales rocketed to over 800,000 copies worldwide[citation needed]. The Grammy Award-winning single "B.Y.O.B.", which questions the integrity of war, worked its way up the Billboard Modern Rock and Mainstream Rock charts. The next single, "Question!" was released with Shavo Odadjian co-directing the music video. Following the release of Mezmerize, the band toured extensively throughout the United States and Canada with The Mars Volta and Bad Acid Trip supporting.
The second part of the double album, Hypnotize, was released on November 22 2005. Like Mezmerize, it debuted at #1 in the US, making System of a Down, along with the Beatles, rapper 2Pac, and rapper DMX, the only artists to ever have two studio albums debut at #1 in the same year. Their second single off the Hypnotize album, "Lonely Day" was released in March in the United States. System Of A Down released "Kill Rock 'N Roll" as their third. airplay only, single.
In February of 2006, System of a Down won the Grammy for Best Hard Rock Performance for "B.Y.O.B.", beating out other established artists such as Nine Inch Nails and Robert Plant. The band headlined Ozzfest 2006 in cities where tour founder Ozzy Osbourne opted not to appear or wasn't playing on the main stage.